[发明专利]荧光材料Zn(hfoac)2(phen)H2O及合成方法

权利要求书

1.一种荧光材料Zn(hfoac)₂(phen)H₂O，其特征在于Zn(hfoac)₂(phen)H₂O的分子式为：C₂₆H₁₈F₂N₂O₇Zn,分子量为：573.81,H₂foac为4-氟水杨酸,phen为邻菲罗啉,晶体结构数据见表一,键长键角数据见表二；Zn(hfoac)₂(phen)H₂O在280nm的入射光照射下产生182a.u.强度的377nm的荧光；

所述Zn(hfoac)₂(phen)H₂O的合成方法具体步骤为：

将0.108g-0.43g分析纯的4-氟水杨酸、0.099-0.396g分析纯的邻菲罗啉和0.11-0.438g分析纯的二水合乙酸锌混合,溶于10-40mL分析纯甲醇溶液中,搅拌10分钟后加入分析纯三乙胺调节pH为7.5,继续搅拌20分钟后,将得到的溶液放于120℃的烘箱中静置120小时后,冷却得到无色的块状晶体即Zn(hfoac)₂(phen)H₂O；

表一：Zn(foac)₂(phen)H₂O的晶体学参数

表二：Zn(foac)₂(phen)H₂O的键长和键角(°)

Zn1-O21.986(2)C2-C31.358(5)Zn1-O12.054(3)C2-C11.391(5)Zn1-O52.061(2)C2-H20.9300Zn1-N22.106(3)C15-C161.360(5)Zn1-N12.139(3)C15-H150.9300O5-C261.261(4)C4-C31.393(5)O2-C191.272(4)C4-C51.431(5)

F1-C161.357(4)C16-C171.368(5)O1-H1A0.8500C10-C91.386(5)O1-H1B0.8500C10-H100.9300F2-C231.351(4)C5-C61.337(5)O6-C261.258(4)C5-H50.9300O3-C191.252(4)C7-C81.397(5)O4-C141.347(4)C7-C61.430(5)O4-H40.8200C18-C171.384(5)O7-C211.345(4)C18-H180.9300O7-H70.8200C1-H10.9300N2-C101.322(4)C21-C221.389(5)N2-C111.364(4)C8-C91.363(5)N1-C11.321(4)C8-H80.9300N1-C121.354(4)C9-H90.9300C12-C41.404(4)C6-H60.9300C12-C111.429(4)C3-H30.9300C19-C131.487(4)C23-C221.362(6)C20-C251.396(5)C23-C241.365(6)C20-C211.397(4)C25-C241.373(5)C20-C261.484(4)C25-H250.9300C11-C71.399(4)C17-H170.9300C13-C181.387(5)C24-H240.9300C13-C141.402(4)C22-H220.9300C14-C151.382(5)  O2-Zn1-O1110.30(12)C3-C4-C5124.3(3)O2-Zn1-O5101.01(9)C12-C4-C5118.9(3)O1-Zn1-O589.03(10)F1-C16-C15118.5(4)O2-Zn1-N2110.54(10)F1-C16-C17118.2(4)O1-Zn1-N2138.98(12)C15-C16-C17123.3(3)O5-Zn1-N286.87(9)N2-C10-C9123.3(3)O2-Zn1-N199.79(9)N2-C10-H10118.3O1-Zn1-N191.39(11)C9-C10-H10118.3O5-Zn1-N1157.64(9)C6-C5-C4121.6(3)N2-Zn1-N178.21(10)C6-C5-H5119.2C26-O5-Zn1128.2(2)C4-C5-H5119.2C19-O2-Zn1118.0(2)C8-C7-C11117.2(3)Zn1-O1-H1A109.8C8-C7-C6123.8(3)Zn1-O1-H1B109.1C11-C7-C6119.0(3)H1A-O1-H1B109.5C17-C18-C13121.4(3)C14-O4-H4109.5C17-C18-H18119.3C21-O7-H7109.5C13-C18-H18119.3C10-N2-C11117.7(3)N1-C1-C2122.9(3)C10-N2-Zn1128.3(2)N1-C1-H1118.5C11-N2-Zn1113.99(19)C2-C1-H1118.5C1-N1-C12117.8(3)O7-C21-C22118.2(3)C1-N1-Zn1129.0(2)O7-C21-C20121.8(3)C12-N1-Zn1113.0(2)C22-C21-C20120.0(4)N1-C12-C4123.0(3)C9-C8-C7120.0(3)N1-C12-C11117.6(3)C9-C8-H8120.0C4-C12-C11119.4(3)C7-C8-H8120.0O3-C19-O2123.5(3)C8-C9-C10119.1(3)O3-C19-C13118.8(3)C8-C9-H9120.5O2-C19-C13117.6(3)C10-C9-H9120.5C25-C20-C21118.2(3)C5-C6-C7120.9(3)C25-C20-C26120.6(3)C5-C6-H6119.5C21-C20-C26121.2(3)C7-C6-H6119.5N2-C11-C7122.7(3)C2-C3-C4120.1(3)N2-C11-C12117.1(3)C2-C3-H3120.0C7-C11-C12120.2(3)C4-C3-H3120.0C18-C13-C14118.6(3)F2-C23-C22118.1(4)C18-C13-C19121.4(3)F2-C23-C24118.4(4)C14-C13-C19120.0(3)C22-C23-C24123.5(4)O6-C26-O5123.6(3)C24-C25-C20122.0(3)O6-C26-C20118.5(3)C24-C25-H25119.0O5-C26-C20117.8(3)C20-C25-H25119.0O4-C14-C15117.5(3)C16-C17-C18117.8(3)O4-C14-C13122.4(3)C16-C17-H17121.1

C15-C14-C13120.1(3)C18-C17-H17121.1C3-C2-C1119.3(3)C23-C24-C25117.5(4)C3-C2-H2120.4C23-C24-H24121.3C1-C2-H2120.4C25-C24-H24121.3C16-C15-C14118.9(3)C23-C22-C21118.8(4)C16-C15-H15120.5C23-C22-H22120.6C14-C15-H15120.5C21-C22-H22120.6C3-C4-C12116.9(3)  

表三：Zn(foac)₂(phen)H₂O的氢键键长和键角(°)

D-H···AD-HH···AD···AD-H···AO1-H1A···O30.852.342.911(4)125O1-H1B···O60.851.932.690(4)148O4-H4···O30.821.812.535(3)147O7-H7···O60.821.822.550(4)147